表面形貌对粗糙接触界面流体润滑特性的影响

为探究不同表面形貌对粗糙接触界面液体润滑特性的影响，基于有限差分法结合雷诺方程和膜厚方程，研究阶梯形貌、波纹形貌、随机形貌和峡谷形貌4种不同粗糙接触界面液体润滑时的载荷分布及规律。研究发现：4种粗糙表面的三维载荷分布规律都与其表面形貌相对应，在波“峰”处载荷大，摩擦力随载荷的增大而增大，在波“谷”载荷小，摩擦力随载荷减小而减小；4种粗糙表面的载荷随表面展开面积比的变化趋势却有所不同；随表面展开面积比的增大，阶梯形貌表面的载荷呈线性增大，波纹形貌表面的载荷基本不变，随机分布形貌表面的载荷呈增大趋势，峡谷形貌表面的载荷呈先增大后减小的变化趋势。研究结果可以进一步补充现有表面形貌表征和流体润滑等相关研究理论。     

YC12VC型高速柴油机发火顺序的分析研究

基于AVL-EXCITE软件搭建了YC12VC发电用高速柴油机轴系动力学模型,其模拟值与试验值吻合性较好,验证了该模型可以较好地模拟不同工况条件下轴系的运动情况。基于平衡性和均匀发火等原则,设计了8种不同的发火顺序,并针对轴承受力、轴承润滑、轴系扭振和转速不均匀性开展影响规律研究。结果表明:通过发火顺序的优化,在保证最大主轴承负荷和最小油膜厚度满足设计要求的前提下,标定工况下的曲轴扭振总振幅从0.465°降低到0.259°,转速不均匀系数从0.018降低到0.009。     

Influence of nucleating agents on crystallization and electrical properties of SiO2–MgO–MgF2–K2O mica glass-ceramics

The effects of adding ZrO₂ and TiO₂ at the expense of MgF₂ on the crystallization, microstructure, mechanical properties, thermal properties and electrical properties of mica glass-ceramics based on the SiO₂–MgO–MgF₂–K₂O system were investigated by the differential scanning calorimetry (DSC), X-ray powder diffraction (XRD), scanning electron microscopy (SEM), microhardness tester and resistivity tester. The electrical properties were discussed emphatically. The results showed that the additions of ZrO₂ and/or TiO₂ at the expense of MgF₂ effectively increase the viscosity, the glass transition temperatures (T_g) and the crystallization temperatures (T_p) of the glasses. The crystallization activation energy (E_c) of the amorphous glasses varied with the nucleating agents was discussed in depth. It was discovered that the nucleating agents had no effect on the crystal phase type but had a certain effect on the crystallinity and microstructure. Tetrasilicic fluoromica and enstatite were precipitated at different crystallization temperatures. Due to the non-stoichiometric ratio of tetrasilicic fluoromica crystal, the prepared glass-ceramics had high dielectric constant (24.4–34.3) and volume resistivity (>2 × 10¹¹ Ω cm) at 25 ^°C, and the dielectric loss was almost zero.     

Design,simulation, elaboration and luminescence of Tb3+-doped Ba0.84Gd0.16F2.16 fluoroaluminosilicate scintillating glass ceramics

Extensive researches on scintillators have been executed to satisfy the excellent radiation detection materials in broad applications. However, practical application of conventional scintillators is limited due to the limitations of high cost, time-consuming fabrication process and insufficient radioluminescence. Herein, high density precursor glass doped with Tb³⁺ was designed to absorb X-ray efficiently and produce green emission. Molecular dynamics simulation was used to simulate the phase separation process in melting process. Then, Tb³⁺-doped Ba_0.84Gd_0.16F_2.16 glass ceramics (GCs) with excellent structural and optical properties were elaborated by melt quenching technic and further heat treating. Their structural properties, photoluminescence (PL) and X-ray excited luminescence (XEL) were explored detailedly. The internal quantum efficiency of PL is 64 % in GCs. The XEL intensity is 192 % of that of Bi₄Ge₃O₁₂ (BGO) commercial scintillator. Our results suggest that Ba_0.84Gd_0.16F_2.16:Tb³⁺ GCs might have potential application in X-ray detection.     

高温泵轴承失效分析及润滑可靠性监测系统的应用

某重油催化装置油浆泵采用集中油雾润滑方式,油液监测发现轴承润滑油中的金属元素含量高,并且呈急剧增加的趋势,拆机检查发现油浆泵轴承出现了严重磨损。分析该油浆泵轴承磨损原因,提出了采用稀油润滑和油雾润滑组合方式来改善轴承润滑。同时,采用了大型炼化企业机泵群油液监测平台对关键动设备进行状态监测,有效保证了设备长周期安全运行。     

悬浮于润滑油中的颗粒运动分析及其对油膜压力的影响

对含有固体颗粒的局部润滑流域建立格子Boltzmann(LBM)离散模型,分析固体颗粒在润滑油中的动力学特性;考虑颗粒形状的影响,推导计入单个固体颗粒运动的润滑方程,并分析得到油膜压力;将油膜流动特性与颗粒动力学计算相结合,分析不同形状的颗粒运动对于油膜压力的影响。分析发现,当颗粒进入润滑油后,经过很短的瞬时颗粒就会达到一个瞬态稳定的状态,无论颗粒在油膜厚度方向的初始位置位于两壁面之间的中线上侧还是下侧,颗粒都会向中线位置移动;当颗粒速度为0时对于油膜压力的影响较大,随着颗粒速度逐渐增大,颗粒对于油膜压力的影响逐渐减小;当颗粒的宽度在油膜厚度方向相同时,长宽比越大的颗粒对于油膜压力的影响也越大;当颗粒长轴相等时,颗粒在油膜厚度方向的宽度越大,则其对于油膜压力的影响也越大,即颗粒形状对于油膜流动的阻碍能力越强,则其对于油膜压力的影响越大。     

链条套筒与销轴铰链副冲击载荷-往复运动的弹流润滑数值模拟

数值模拟链传动中销轴与套筒之间的定载荷和变载荷弹流润滑接触问题,套筒相对于销轴做纯滑动往复运动。定载荷是假定往复运动过程中载荷恒定不变;变载荷是假定链节在啮入和啮出链轮过程中存在的冲击载荷按正弦函数规律变化。比较在定载荷和变载荷加载条件下线接触往复运动工况的弹性润滑油膜变化情况,分析在动载荷加载条件下不同行程长度对弹性流体动力润滑特性的影响。研究发现,动载荷对油膜的压力、膜厚影响较大:随着动载荷的增加,油膜中压力急剧增大,膜厚减小;但加载方式对摩擦因数的影响不大;在相同的加载方式下,随着行程长度的增加,油膜压力减小,中心膜厚和最小膜厚显著增加。     

Mechanical,surface morphological and multi-objective optimization of tribological properties of V2O5 doped lead calcium titanate borosilicate glass ceramics

In the 55[(Pb_xCa_1−x).OTiO₂]-44[2SiO₂.B₂O₃]-1V₂O₅ system, various experimental studies were performed to obtain the mechanical and tribological properties of synthesized glass ceramics (GCs). The surface morphological study and elemental analysis were carried out using scanning electron microscope (SEM) followed by EDAX. The tribological measurements were also performed; based on Taguchi's L₂₅ orthogonal array, considering different GC compositions, sliding speeds and loads. The signal to noise (S/N) ratio was used to identify the influencing parameters on minimizing wear coefficient (k) and coefficient of friction (COF). To improve the tribological properties, the modeling of output responses was performed using response surface methodology (RSM) that was being used for multi-objective optimization using a Pareto optimality approach i.e. Genetic Algorithm (GA). The experimentally achieved k and COF were compared with the earlier work that carried out by the authors for germanium (Ge) doped GC samples. It is observed that the various mechanical properties (Vickers hardness, 29 GPa, Young's modulus, 1808 MPa, and compressive strength, 221 MPa) improved significantly in comparison to the Ge doped GC samples. The improved mechanical and tribological properties of the synthesized GC can be used as a coating material for the structural alloys and machine tool slides in view of its effective wear and corrosion resistance.     

Effects of pyrochlore content on the phase,structure, and properties of uranium-rich glass ceramics

In this study, the effects of the pyrochlore content on the phase, structure, and properties of uranium-rich glass ceramics were studied by modifying the mass ratio of the uranium pyrochlore in the glass ceramics. The results indicate that U has a high occupancy rate of approximately 0.7 f.u. at the A position of pyrochlore, and the crystal pyrochlore phase in the glass matrix can increase or decrease according to the U amount in the waste. Specifically, at a high occupancy rate and crystallization amount, the U loads reach 20 wt% in the sample, which exceeds the reported 16 wt% maximal U loads of pyrochlore-based glass ceramics. Furthermore, all the samples have excellent mechanical properties and chemical stabilities. The bulk density of each sample is more than 90% the theoretical density, which is 10–20% higher than those of the glass ceramics prepared by pressure sintering. Moreover, the Vickers hardness values of all samples exceed 6 GPa, and the U leaching rate after 21 days is only 6.7 × 10⁻⁵ g m⁻² d⁻¹, which is an order of magnitude lower than those of brannerite glass ceramics under equal leaching conditions.     

Weatherability of hybrid organic–inorganic silica protective coatings on glass

Currently, there is a growing interest in the application of silicon-based technologies for the development of advanced hybrid organic–inorganic coatings with strong weatherability. In this study, the sol–gel process is used to prepare such coatings on glass and their resistance to weathering effects is assessed afterwards. Various sols were prepared by mixing a silica-based inorganic matrix (tetraethyl orthosilicate) with different quantities of silica alkoxides functionalised with various organic groups. Subsequently, the sols were dip-coated onto glass samples at low temperatures without any heat treatment. The coatings prepared were analysed before and after three model ageing tests simulating various weathering parameters. After ageing, the best performing coatings showed good overall homogeneity and transparency (optical microscopy, SEM), improved water repellency and adhesion to the glass substrate (static contact angle measurements, cross-cut tape tests) and no colour or chemical composition changes (UV–VIS, FTIR). Compared with commercial hybrid silica products, the alkyl- and methacryloxy-functionalised silica coatings particularly displayed improved homogeneity, elasticity and barrier properties. Thus, these low temperature coatings, easily applicable to thin films, appear to fulfil the main requirements for the protection of the glass exposed to weathering phenomena.